One-step Multi-electron Transfer Reaction of Organic Molecules Based on Potential Inversion Process
نویسندگان
چکیده
منابع مشابه
Electron-Transfer Boat-Vibration Mechanism for Superconductivity in Organic Molecules Based on BEDT-TTF
The highest T, organic superconductors all involve the organic molecule bis(ethy1enedithio)tetrathiafulvalene (denoted as BEDT-TTF or ET) coupled with an appropriate acceptor. This leads to ET, ET+, or (ET)2+ species in the crystal. Using ab initio Hartree-Fock calculations (6-31G** basis set), we show that ET deforms to a boat structure with an energy 28 meV (0.65 kcallmol) lower than that of ...
متن کاملORGANIC SYNTHESIS Synthesis of many different types of organic small molecules using one automated process
Small-molecule synthesis usually relies on procedures that are highly customized for each target. A broadly applicable automated process could greatly increase the accessibility of this class of compounds to enable investigations of their practical potential. Here we report the synthesis of 14 distinct classes of small molecules using the same fully automated process. This was achieved by strat...
متن کاملElectron-transfer through potential gradient based on a dendrimer architecture.
A dendritic nano-shell based on rigid phenylazomethine units can rectify electron transfer. By use of this function, the photo-induced charge separation was significantly enhanced due to the facilitated and stabilized radical ion pair.
متن کاملsingle-step synthesis of multi-component spirobarbiturates using ionic liquids and synthesis of substituted pyridine filled with catalysts supported on solid substrate
in this thesis, a better reaction conditions for the synthesis of spirobarbiturates catalyzed by task-specific ionic liquid (2-hydroxy-n-(2-hydroxyethyl)-n,n-dimethylethanaminium formate), calcium hypochlorite ca(ocl)2 or n-bromosuccinimide (nbs) in the presence of water at room temperature by ultrasonic technique is provided. the design and synthesis of spirocycles is a challenging task becaus...
15 صفحه اولA reagentless biosensor of nitric oxide based on direct electron transfer process of cytochrome c on multi-walled carbon nanotube.
Direct electron transfer between Cytochrome c (Cyt.c) and electrode can be achieved through immobilizing Cyt.c on the surface of multi-walled carbon nanotubes (MWNTs). Under the condition of cyclic potential scans, Cyt.c can be adsorbed on the surface of MWNTs that were modified on a glassy carbon (GC) electrode to form an approximate monolayer. The redox characteristic and bioactivity of Cyt.c...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Review of Polarography
سال: 2010
ISSN: 0034-6691
DOI: 10.5189/revpolarography.56.81